Hempcrete 2

🧱 How to Make Hempcrete (Hemp Concrete)

🔹 Materials Needed

  • Hemp hurds (shives) → chopped woody core of the hemp stalk (particle size ~5–25 mm).
  • Binder → hydrated lime, natural hydraulic lime (NHL), or lime-pozzolan mix (some recipes add ~10% Portland cement, but pure lime is more traditional and eco-friendly).
  • Water → clean, potable.

Typical Ratio (by volume):

  • 1 part binder
  • 1.5 parts hemp hurds
  • 3 parts water

(Some builders adjust to 1:3:1.5 binder:hemp:water depending on density and application.)


🔹 Tools Needed

  • Large mixing container (wheelbarrow, concrete mixer, or paddle mixer)
  • Measuring buckets
  • Shovel or mixing paddle
  • Molds or formwork (for blocks, walls, or panels)
  • Protective gear (gloves, dust mask, safety glasses – lime is caustic)

🔹 Step-by-Step Instructions

  1. Prepare Materials
    • Make sure hemp hurds are dry and clean.
    • Pre-measure binder and water for consistency.
  2. Mix the Binder and Water
    • Slowly add water to the lime binder while stirring until it becomes a smooth, workable paste.
    • The mix should be moist but not soupy.
  3. Add Hemp Hurds
    • Gradually add hemp hurds to the lime-water mix.
    • Stir gently so the lime coats the fibers evenly.
    • Do not overmix – it can break down the hurds.
  4. Check Consistency
    • The mixture should clump together when squeezed, but not drip water.
    • Adjust water if needed (too dry → add a little water, too wet → add more hemp).
  5. Place into Formwork
    • Pour or hand-place the hempcrete into molds, block forms, or wall shuttering.
    • Lightly tamp down by hand or with a stick – just enough to remove air pockets.
    • Do not compress too much, as hempcrete needs air gaps for insulation and breathability.
  6. Curing
    • Remove forms after 1–2 days (if making blocks).
    • Allow to cure at least 4–6 weeks before applying plaster, render, or load.
    • Protect from rain and frost during curing (cover with breathable sheets).

🔹 Key Properties

  • Lightweight and insulating (R-value varies with density).
  • Fire-resistant.
  • Mold and pest resistant.
  • Carbon-negative: lime absorbs CO₂ during curing.

🧱 DIY Small-Batch Hempcrete (Home / Experiment Size)

Materials (for ~1 block, 30 × 30 × 15 cm)

  • Hemp hurds: ~6 liters (about a small bucket)
  • Binder (hydrated lime or NHL): ~2 liters
  • Water: ~4 liters

Tools

  • 1 mixing bucket or wheelbarrow
  • Shovel or paddle mixer
  • Simple wooden mold (can be a box with no top or bottom)
  • Gloves, mask, goggles (lime safety)

Steps

  1. Mix binder + water until smooth paste.
  2. Add hemp hurds gradually, stir until coated.
  3. Fill mold with mixture, lightly tamp (don’t compress hard).
  4. Leave in mold 1–2 days, then carefully remove.
  5. Cure in a dry, ventilated place for 4–6 weeks.

👉 After curing, you’ll have a lightweight insulating block you can test.


🏗️ Industrial-Scale Hempcrete (Construction Use)

Materials (per cubic meter of hempcrete)

  • Hemp hurds: 100–120 kg
  • Binder (lime mix or NHL): 220–250 kg
  • Water: 200–250 liters

(Exact ratios vary depending on density needed – wall insulation vs. structural infill.)

Equipment

  • Industrial lime mixer or pan mixer (not a drum cement mixer — it can break hemp fibers)
  • Conveyor or pumping system for large pours
  • Shuttering/formwork for walls or block-making molds
  • Forklift/pallet system for block curing and storage

Steps

  1. Pre-mix binder + water in large industrial mixer.
  2. Add hemp hurds in batches, mix just enough for even coating.
  3. Deliver mixture into wall formwork or molds using conveyors/pumps.
  4. Light tamping to eliminate air voids but preserve breathability.
  5. Curing
    • Keep protected from direct rain/sun.
    • Curing time ~6–8 weeks for full strength.
    • CO₂ absorption continues for months, improving durability.

Scaling

  • Continuous mixing systems allow on-site spraying of hempcrete into wall cavities.
  • Industrial block production lines can press, demold, and cure thousands of hempcrete blocks for construction markets.

⚡ Comparison:

AspectDIY / Small BatchIndustrial / Large Scale
Batch size1 block or a few liters1 m³ = enough for ~4 m² wall
Mixing toolBucket + shovelPan mixer / continuous spray system
CostLow, home experimentHigher, but scalable and commercial
Cure time4–6 weeks6–8 weeks (walls dry slower than blocks)
ApplicationSmall eco-projects, testingFull homes, insulation systems, prefabs

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Hemp Batteries

A “hemp battery” usually refers to an energy storage device that uses hemp-based materials (especially hemp bast fiber or hurd) in place of traditional graphite electrodes. Hemp is promising because its fibers contain carbon-rich structures that can be turned into nanosheets, which act like graphene but are cheaper and more sustainable.

Here’s a breakdown of how researchers have made hemp-based supercapacitors or batteries:


1. Gather the raw hemp material

  • Bast fibers (the stringy outer bark of the stalk) are most often used.
  • These fibers have a high lignin and cellulose content that can be transformed into conductive carbon.

2. Carbonization (turning hemp into conductive carbon)

  • Process: Heat hemp fibers in a furnace at very high temperatures (700–800 °C or more) in the absence of oxygen (a process called pyrolysis).
  • This burns off non-carbon elements and leaves behind a porous carbon structure.
  • Some researchers use hydrothermal carbonization (in pressurized hot water at 180–250 °C) first, then further heat-treat the material to improve conductivity.

3. Creating nanosheets

  • If done correctly, the carbonized hemp fibers form graphene-like nanosheets.
  • These nanosheets have very high surface area, which is ideal for holding electrical charge.

4. Assembling the battery (or supercapacitor)

  • Electrodes: Use the hemp-derived carbon nanosheets as the electrodes.
  • Electrolyte: A salt-based liquid or gel (commonly KOH, H₂SO₄, or ionic liquids for supercapacitors; lithium salts for lithium-ion batteries).
  • Separator: A thin membrane that keeps the positive and negative electrodes from touching but allows ions to pass through.
  • Current collectors: Thin pieces of conductive metal (like aluminum or copper foil) that connect the electrodes to the outside circuit.

5. Testing performance

  • Hemp-based carbons have shown:
    • Very high capacitance (better energy storage compared to many conventional carbons).
    • Fast charging/discharging.
    • Lower cost than mined graphite or lab-grown graphene.

⚠️ Note: Building a functional hemp-based supercapacitor or battery at home is very difficult and potentially dangerous, since it requires high-temperature furnaces, controlled atmospheres, and chemical handling. But in a lab or startup setting, hemp electrodes are a sustainable path forward.

Awesome—here’s a practical, industrial-scale playbook to manufacture hemp-derived carbon electrodes for two product lines:

  1. EDLC supercapacitors (activated hemp carbon, very high surface area)
  2. Sodium-ion (Na-ion) hard-carbon anodes (from hemp hurds/bast)

I’ll lay out the process flow, equipment, key parameters, QA, EHS, and cost levers. Where performance/conditions could be contentious or have changed recently, I’ve cited current literature and dry-room norms.


0) Product choices & what changes between them

EDLC supercapacitors (hemp → activated carbon):

  • Goal: ultra-high surface area (1,800–2,500 m²/g) and meso/micro-porosity distribution tuned for fast ion access. KOH/CO₂/steam activation after carbonization is typical. Hemp bast–derived carbons have delivered graphene-like performance at a fraction of cost. PubMedScienceDailyNew Atlas

Na-ion battery anodes (hemp → hard carbon):

  • Goal: “hard carbon” with appropriate microstructure (disordered/“house-of-cards” graphitic domains), low surface area (to reduce SEI), optimized pore distribution to hit reversible capacities (e.g., 280–350 mAh/g) and flat low-voltage plateau. Hemp hurds/bast are among validated biomass precursors. American Chemical Society PublicationsScienceDirect+1

Key divergence: EDLC pushes high surface area via strong activation; Na-ion anode pushes moderate/low surface area and dense structure (often skip harsh activation or use very controlled activation/templating).


1) End-to-end process (block flow)

Feed handling → Decortication/Cleaning → Size reduction → Drying → (Optional) Hydrothermal carbonization → Pyrolysis/Carbonization → (Activation: KOH/CO₂/Steam) → Acid wash/Neutralization → Drying → Milling/Classification → Electrode slurry prep → Coating on foil → Drying → Calendaring → Slitting → Cell assembly (dry room) → Electrolyte fill/Formation → Testing/packaging*

Activation is on for EDLC; off or very mild for Na-ion hard carbon.


2) Unit operations, equipment, & target conditions

A) Biomass prep

  • Raw material: hemp bast fibers (EDLC) and/or hurds (Na-ion).
  • Decorticator (drum/hammer-type), air classifier, magnetic trap.
  • Washer (counter-current water wash) to reduce ash/metal content (<1 wt% preferred).
  • Dryer: belt or rotary; 105 °C outlet; target moisture <8 wt%.

B) (Optional) Hydrothermal carbonization (HTC) – improves yield & morphology control

  • Autoclaves (stainless, stirred) at 180–250 °C, 1–4 h, water:biomass 5–10:1.
  • Filter, wash, dry to <10 % moisture. Often used in Na-ion pathways for uniformity. ScienceDirect

C) Primary carbonization (pyrolysis)

  • Continuous inert-gas rotary kiln or multi-hearth furnace.
  • Atmosphere: N₂ or Ar, O₂ <100 ppm.
  • Ramp: 2–10 °C/min to 700–1,000 °C; hold 1–2 h; off-gas to thermal oxidizer for VOC/CO cleanup and heat recovery.
  • Outcome: biochar with 60–80 % fixed carbon, tunable microstructure.

D1) EDLC activation (hemp → activated carbon)

Choose KOH chemical activation (highest SSA) or physical activation (CO₂/steam).

  • KOH activation (most common for top capacitance):
    • Impregnation: biochar:KOH 1:3–1:5 by mass in aqueous solution; mix 1–2 h; dewater to 30–40 % solids; dry to <5 % H₂O.
    • Activation furnace: 750–850 °C, N₂, 0.5–1.5 h.
    • Reactions etch micro/mesopores; K intercalation expands lattice.
    • Acid wash: multiple rinses with 5–10 wt% HCl until filtrate <10 ppm K; DI water to neutral pH.
    • Drying: tray/vacuum dryer, <100 °C. Target SSA 1,800–2,500 m²/g; tune pore size distribution for chosen electrolyte. ScienceDirectChemistry Europe
  • CO₂/Steam activation (greener but lower SSA at given conditions):

D2) Na-ion hard carbon (hemp → hard carbon)

  • Typically no harsh activation; instead:
    • Higher-temp carbonization: 1,100–1,300 °C (some go 1,400–1,500 °C) for 1–3 h to reduce defects/surface area (BET often <10 m²/g), build closed pores for plateau capacity.
    • Optionally mild activation or doping (e.g., N-doping via urea) to tweak initial Coulombic efficiency (ICE) and rate. American Chemical Society PublicationsScienceDirect

E) Post-processing

  • Jet mill / classifier to D50 ~5–15 µm (EDLC) or ~5–10 µm (Na-ion HC); narrow PSD is key for slurry stability.
  • Ash check: aim <0.3 wt%; repeat acid wash if needed for EDLC carbons.

F) Electrode fabrication

  • Binders & solvents
    • EDLC: AC + PTFE (dry fibrillation) or PVDF (NMP) or water-based (CMC/SBR).
    • Na-ion anode (HC): water-based CMC/SBR is common (safer, cheaper); solids 40–55 wt%.
  • Conductive additive: small % carbon black or CNTs (often 1–5 %).
  • Current collectors:
    • EDLC: Al foil (10–20 µm).
    • Na-ion anode: Cu foil (6–12 µm) unless using Al-compatible chemistries.
  • Coating: comma/slot-die to target areal loading (EDLC: 5–12 mg/cm²; HC anode: 2–5 mAh/cm² equivalent).
  • Drying: 80–120 °C (water) or 120–150 °C (NMP recovery via solvent condenser).
  • Calendaring: target porosity 25–40 % (EDLC), 30–40 % (HC anode).
  • Slitting to jelly-roll or stacked formats.

G) Cell assembly (dry room), fill & formation

  • Dry room dew point: ≤ −40 °C typical; some lines run −45 to −60 °C; electrolyte fill zones can push ≤ −60 to −80 °C. Temperature ~20–23 °C. (These targets are industry-standard ranges; vendors differ.) Angstrom TechnologyAfryCharged EVsCleanroom Technology
  • EDLC electrolyte: e.g., 1 M TEABF₄ in acetonitrile or aqueous KOH/H₂SO₄ (if designing aqueous EDLC).
  • Na-ion electrolyte: e.g., 1 M NaPF₆ in EC/DEC or PC with additives; separator: polyolefin or glass fiber (pilot).
  • Formation:
    • EDLC: polarization/leakage/ESR check; 2–3 step voltage holds.
    • Na-ion: gentle formation cycles (e.g., C/20 to C/10) to build a stable SEI and raise ICE.

3) Performance targets (indicative)

  • EDLC electrode from hemp-activated carbon:
    • SSA: 1,800–2,500 m²/g; capacitance >250–350 F/g (3-electrode in 6 M KOH; lower in full cell), low ESR. Literature has reported high performance from hemp-derived nanosheets/activated carbons vs graphene at far lower cost. PubMedScienceDailyScienceDirect
  • Na-ion hard carbon anode from hemp hurds/bast:

4) Quality control (inline & lot release)

Incoming hemp

  • Moisture, ash, metals (ICP-OES), fiber/hurd ratio, pesticide screen (where required).

Carbon/intermediates

  • BET/BJH surface area & pore size distribution (EDLC).
  • Raman (ID/IG), XRD (d002) for graphitization; TGA for volatile/fixed carbon.
  • Elementals (CHNS), ICP-OES for residual K/Cl/Fe.
  • PSD (laser diffraction); tap density.

Electrodes

  • Coating weight (g/m²), thickness/porosity, adhesion (peel), resistivity (4-point), binder distribution (SEM/EDS).

Cells

  • EDLC: capacitance at rated voltage, ESR, leakage current, life test (e.g., 1,000–10,000 hours at 65 °C/VR).
  • Na-ion: formation ICE, capacity retention (e.g., >80% after 500 cycles target depends on chemistry), rate, impedance growth.

5) Environmental, health & safety (EHS)

  • High-temp furnaces: interlocked N₂/Ar purge, CO and O₂ monitoring; ATEX zoning at activation off-gas.
  • KOH handling: closed dissolvers, PPE, acid neutralization of effluents; recycle K salts if feasible.
  • Acetonitrile/PC/EC/DEC/NMP: explosion-proof rooms, solvent recovery systems, activated-carbon abatement on vents.
  • Dry room: desiccant rotor + chiller, dew-point monitoring, airlocks and gowning; Li/Na salts are moisture-sensitive. (Vendors and white papers detail modern specs and trends.) Cleanroom Construction AssociatesAtomfair

6) Capacity & cost levers (back-of-envelope)

  • Yields: biomass → biochar 25–35% (depends on HTC and temperature); activation burn-off reduces mass further (EDLC net yield from biomass can be 5–15% depending on severity).
  • CapEx drivers: furnaces (carbonization/activation), dry-room/HVAC, solvent recovery, coating/calendaring lines, formation.
  • OpEx drivers: nitrogen/argon, KOH/acid/water, electricity (furnaces + HVAC), solvents/electrolyte, waste neutralization, labor.
  • Where hemp helps: lower precursor cost and local sourcing; hurds are often a low-value by-product. Hemp-derived carbons have matched or beaten graphene/graphite in certain EDLC metrics at orders-of-magnitude lower precursor cost. New Atlas

7) Process tuning tips

  • EDLC:
    • Raise activation severity (higher KOH ratio / temperature / time) → ↑SSA but watch ESR and mechanical strength.
    • Tailor pore distribution to electrolyte ion size (organic vs aqueous). ScienceDirect
  • Na-ion HC:
    • Higher final carbonization (≥1,200 °C) → lower surface area, better plateau capacity, higher ICE; too high can reduce capacity by collapsing useful pores.
    • Mild heteroatom doping can improve rate but may hurt ICE if surface area rises. American Chemical Society PublicationsScienceDirect

8) Example bill of process equipment (one 1,000 t/y electrode plant)

  • Decorticator + air classifier + washing/press + belt dryer
  • HTC autoclaves (optional)
  • N₂-retort rotary kiln (carbonization, 1–1.5 t/h)
  • Activation furnace (rotary/shaft), acid-wash trains, neutralization tanks
  • Jet mill & classifier
  • Solvent-capable slurry mix room (double-planetary mixers, bead mill)
  • Roll-to-roll coater (slot-die/comma), 1–2 m width; drying oven; NMP recovery if PVDF/NMP used
  • Calendars (200–400 kN/m), slitters
  • Dry room: −40 to −60 °C dp, 20–23 °C, ISO 7–8; assembly lines (winders/stackers)
  • Electrolyte fill + sealing (vacuum), formation cyclers, EoL testers, aging racks

9) Compliance & standards (typical)

  • ISO 9001/14001, ISO 45001.
  • Clean/dry-room design per vendor guidance; common dew-point targets cited above. AfryCharged EVs
  • Chemical handling under REACH/TSCA as applicable; wastewater permit for neutralized brines.

10) Where to start your pilot

  1. Pick the lane: EDLC vs Na-ion anode (they want different microstructures).
  2. Pilot furnaces (50–200 kg/batch) to lock T-t-gas recipes and activation severity.
  3. Build a pilot coating line (200–500 mm web) to tune slurry rheology, adhesion, porosity, and calender setpoints.
  4. Bring up a small dry room (−40 °C dp) for assembly & formation.

If you tell me which lane (EDLC vs Na-ion) and the annual output target, I’ll sketch a first-pass mass & energy balance with equipment sizing and a capex/opex rough-cut.

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Patio Preparation

Ante Bosko stands at the edge of the job site, steel-toed boots in gravel, sun hitting the gold chain on his chest. He claps his hands to get the crew’s attention. Around him are pallets of paving stones, a wheelbarrow full of sand, and a Bluetooth speaker quietly playing 80s rock.

“Alright, listen up, gentlemen. This is how we build a proper patio—Bosko style.”

He points to the ground, marking out the vision in the air with his calloused hands.

“First, you excavate clean and flat. No shortcuts. Six inches minimum—gravel base compacted tight like your mother’s cabbage rolls. Then the bedding sand—screeded level, smooth like silk. After that, we lay the pavers tight, like bricks in the Old Town of Dubrovnik. No gaps, no dancing stones.”

He walks over, picks up a paving stone, holds it like a sacred object.

“Every stone has its place. It’s like a mosaic. It has to flow. And when we’re done? Polymeric sand in the joints, plate compactor over the top, and that patio’s locked in like a tank.”

He wipes the sweat from his brow, then points toward the patio entrance.

“But let me be clear—the customer puts up the patio lanterns. We don’t do fairy lights. We build the stage. If they want romance, that’s on them.”

The crew laughs. One guy yells, “No lanterns, no love!”

Ante smiles, lights the cigarette behind his ear, and says:

“Exactly. We build the bones. They bring the candles. Now let’s make it shine, boys.”

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